Título del artículo:

Optimizing hydrogen production and efficiency in biomass gasification through advanced CFD modeling

Gasification is a thermochemical process that converts biomass into biochar, bio-oil, and syngas. This study applies Computational Fluid Dynamics (CFD) to predict Cold Gas Efficiency (CGE) and hydrogen yield (yH2), integrating a pyrolysis submodel and an average intrinsic reactivity approach for solid–gas reactions to assess the influence of temperature on gas composition and reaction kinetics. A two-dimensional downdraft gasifier model was developed to simulate species transport and reaction mechanisms under four experimental treatments: gasification with air (B), with CaCO3 as a catalyst (BC), with steam addition (BS), and with both steam and CaCO3 (BCS). Model validation demonstrated that CFD accurately captured the effects observed experimentally, predicting syngas composition with a global error of 7.71 %. The highest CGE achieved was 61.6 %, and the maximum yH2 reached 308 ml H2/g biomass under the BCS condition, where the combination of steam and CaCO3 enhanced hydrogen production by promoting tar reforming and CO2 capture. The results confirm that steam and CaCO3 improve cold gas efficiency and hydrogen yield, aligning with experimental observations. This study highlights CFD as a reliable tool for predicting biomass gasification performance, particularly for hydrogen-rich syngas production.

Acerca de la revista donde se publicó este artículo:

Applied Thermal Engineering